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Dr. Rafael Gramage-Doria, Rosalba Bellini, Jeroen Rintjema and Prof. Dr. Joost N. H. Reek Supramolecular Ligands in Gold(I) Catalysis ChemCatChem 5

Version of Record online: 25 OCT 2012 | DOI: 10.1002/cctc.201200541

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Golden (I): A supramolecular ligand–template strategy is applied to gold(I) catalysis. The supramolecular ligands, formed from a phosphoramidite backbone and two templates, display different regioselectivity in the hydroalkoxylation of allenes compared to non-supramolecular analogues. Based on these findings, the catalytic activity of gold(I) complexes could be tunable at a supramolecular level.

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