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Dr. Jie Wang, Dong-Minh Do, Prof. Dr. Gaik-Khuan Chuah and Prof. Dr. Stephan Jaenicke Core–Shell Composite as the Racemization Catalyst in the Dynamic Kinetic Resolution of Secondary Alcohols ChemCatChem 5

Version of Record online: 13 NOV 2012 | DOI: 10.1002/cctc.201200566

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Small is in: The dynamic kinetic resolution of secondary alcohols through enzyme-catalyzed transesterification is performed in a one-pot system. The key is a core–shell composite of Beta–Silicalite-1, in which the nanoporous shell suppresses external acidity and allows only small molecules to access the acid sites of the core Beta zeolite.

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