E-mail

E-mail a Wiley Online Library Link

Dr. Maksym Opanasenko, Dr. Amarajothi Dhakshinamoorthy, Prof. Dr. Jiří Čejka and Prof. Dr. Hermenegildo Garcia Deactivation Pathways of the Catalytic Activity of Metal–Organic Frameworks in Condensation Reactions ChemCatChem 5

Article first published online: 5 FEB 2013 | DOI: 10.1002/cctc.201200643

Thumbnail image of graphical abstract

What is the poison? Three different condensation reactions were chosen as model reaction to determine the nature of the poisons causing structural instability (see picture), and varied product selectivity for two related metal–organic framework catalysts, Fe(BTC) and synthetic MIL-100(Fe). Undesired intermediates or byproducts were found to block the pores, whereas phenolic substrates could substitute the metal ligands thus destabilizing the catalyst structure.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field

SEARCH