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Dr. Antony J. Ward, Cameron C. Weber, Prof. Anthony F. Masters and Prof. Thomas Maschmeyer Application of Bismuth-Impregnated Mesoporous Silica to the Photochemical Oxidation of Methylene Blue: An Example of Nanoparticle Autocatalysis ChemCatChem 5

Version of Record online: 18 FEB 2013 | DOI: 10.1002/cctc.201200669

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Less is sometimes more: The irradiation of a series of bismuth-impregnated mesoporous silicas (Bi-TUD-1) in the presence of peroxide show increasing degradation activity of methylene blue with decreasing bismuth loadings. Kinetic studies reveal that the active sites of the catalyst are generated autocatalytically.

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