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Dr. Chieh-Chao Yang, Dr. Tamara M. Eggenhuisen, Dr. Mariska Wolters, Dr. Anil Agiral, Dr. Heinz Frei, Dr. Petra E. de Jongh, Prof. Dr. Krijn P. de Jong and Prof. Dr. Guido Mul Effects of Support, Particle Size, and Process Parameters on Co3O4 Catalyzed H2O Oxidation Mediated by the [Ru(bpy)3]2+ Persulfate System ChemCatChem 5

Version of Record online: 16 JAN 2013 | DOI: 10.1002/cctc.201200696

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Optimizing the path to oxygen: Co3O4 dispersed in porous silica supports (such as SBA-15 and MCM-41) was found to be active in catalytic water oxidation, yielding O2. Different particle sizes of Co3O4 were synthesized by applying NO, or air calcination conditions. Smaller particles are more active in water oxidation than larger ones.

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