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Dr. Yusuke Mikami, Dr. Amarajothi Dhakshinamoorthy, Dr. Mercedes Alvaro and Prof. Dr. Hermenegildo Garcia Superior Performance of Fe(BTC) With Respect to Other Metal-Containing Solids in the N-Hydroxyphthalimide-Promoted Heterogeneous Aerobic Oxidation of Cycloalkanes ChemCatChem 5

Article first published online: 7 MAR 2013 | DOI: 10.1002/cctc.201200854

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Aerobic oxidation: The N-hydroxyphthalimide (NHPI)-promoted aerobic oxidation of cycloalkanes can be performed by supporting NHPI on high-surface-area solids. Of the materials tested, NHPI incorporated onto commercially available Fe(BTC) (BTC=1,3,5-benzenetricarboxylate) appears to be most efficient due to the balance of high combined selectivity toward -ol/-one products and conversion.

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