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Mireia Rovira, Marc Font and Dr. Xavi Ribas Model C sp 2[BOND]C sp 3 Hurtley Coupling Catalysis that Operates through a Well-Defined CuI/CuIII Mechanism ChemCatChem 5

Version of Record online: 19 FEB 2013 | DOI: 10.1002/cctc.201200885

Thumbnail image of graphical abstract

The Hurtley locker: The first examples of copper-catalyzed Cmath image[BOND]Cmath image cross-coupling with the direct involvement of a CuI/CuIII catalytic cycle are reported. The product rapidly reorganizes into a 1,2-dihydroisoquinoline scaffold.

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