E-mail

E-mail a Wiley Online Library Link

Dr. S. Abate, Dr. M. Freni, Dr. R. Arrigo, Dr. M. E. Schuster, Prof. S. Perathoner and Prof. G. Centi On the Nature of Selective Palladium-Based Nanoparticles on Nitrogen-Doped Carbon Nanotubes for the Direct Synthesis of H2O2 ChemCatChem 5

Article first published online: 2 MAY 2013 | DOI: 10.1002/cctc.201200914

Thumbnail image of graphical abstract

Caps off to gold: High selectivities (>95 %) are obtained if Pd nanoparticles are covered with an organic capping agent, the removal of which during the reaction leads to a decrease in selectivity. With Au, the intrinsic reaction rate decreases but selectivity is better after the removal of the capping agent. The presence of Au creates small Pd terraces fully covered with chemisorbed O2; H2O2 synthesis occurs at the perimeter of these terraces.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field

Choose captcha format: Image or Audio. Click here if you need help.

SEARCH