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Antoine Monassier, Dr. Valerio D'Elia, Dr. Mirza Cokoja, Dr. Hailin Dong, Dr. Jérémie D. A. Pelletier, Prof. Dr. Jean-Marie Basset and Prof. Dr. Fritz E. Kühn Synthesis of Cyclic Carbonates from Epoxides and CO2 under Mild Conditions Using a Simple, Highly Efficient Niobium-Based Catalyst ChemCatChem 5

Version of Record online: 20 FEB 2013 | DOI: 10.1002/cctc.201200916

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Like a sore thumb: Niobium stands out among neighboring transition metals for its catalytic performance in the synthesis of cyclic carbonates. Readily available NbCl5 is a very efficient catalyst for the preparation of industrially relevant carbonates at ambient temperature, low CO2 pressure, and low concentrations. DMAP=N,N-dimethylaminopyridine.

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