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P. Philipp M. Schleker, Roman Honeker, Prof. Dr. Jürgen Klankermayer and Prof. Dr. Walter Leitner Catalytic Dehydrogenative Amide and Ester Formation with Rhenium–Triphos Complexes ChemCatChem 5

Article first published online: 11 APR 2013 | DOI: 10.1002/cctc.201200942

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[Re]ad all about it: The first examples of the rhenium-catalyzed dehydrogenative formation of amides and esters with the highly active ReH5(triphos) complex are demonstrated. The addition of a tertiary amine additive improves the selectivity and the stability of the catalyst in the formation of esters from primary alcohols.

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