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Simone G. Weber, David Zahner, Dr. Frank Rominger and Prof. Dr. Bernd F. Straub Mechanistic Investigations of a Stable, Highly Active, Extremely Sterically Shielded Molecular Gold Catalyst ChemCatChem 5

Article first published online: 25 MAR 2013 | DOI: 10.1002/cctc.201200944

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Deeply buried but very vivid: An unprecedented combination of high activity, stability, selectivity, and Lewis acidity as well as mechanistic insight is provided by the gold bistriflimide complex of an IPr** N-heterocyclic carbene ancillary ligand with its record buried volume.

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