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Daquan Xia, Tanyu Cheng, Wei Xiao, Ketang Liu, Zhaoliang Wang, Prof. Dr. Guohua Liu, Hexing Li and Prof. Dr. Wei Wang Imidazolium-Based Organic–Inorganic Hybrid Silica as a Functional Platform Dramatically Boosts Chiral Organometallics Performance in Asymmetric Catalysis ChemCatChem 5

Article first published online: 10 APR 2013 | DOI: 10.1002/cctc.201200954

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A phase-transfer featured, imidazolium-based, organic–inorganic hybrid silica as a functional platform, is used to develop a bifunctionalized heterogeneous catalyst that displays comparable or higher catalytic activity and enantioselectivity than its homogeneous counterpart in asymmetric transformations. This hybrid silica also boosts asymmetric catalysis and can be recovered conveniently and reused without affecting its catalytic efficiency.

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