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Dr. Yuanbiao Huang, Tao Ma, Dr. Ping Huang, Dongshuang Wu, Dr. Zujin Lin and Prof. Rong Cao Direct C[BOND]H Bond Arylation of Indoles with Aryl Boronic Acids Catalyzed by Palladium Nanoparticles Encapsulated in Mesoporous Metal–Organic Framework ChemCatChem 5

Article first published online: 24 MAY 2013 | DOI: 10.1002/cctc.201200957

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All in a frame's work: The direct C2 arylation of indoles with aryl boronic acids is achieved through the combination of highly dispersed Pd nanoparticles encapsulated in the mesoporous metal–organic framework MIL-101 with O2 or 2,2,6,6-tetramethylpiperidine N-oxyradical (TEMPO) as an external oxidant in acidic media under mild conditions.

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