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Kai Ren, Lei Zhang, Bei Hu, Mengmeng Zhao, Yahui Tu, Dr. Xiaomin Xie, Dr. Tony Y. Zhang and Prof. Zhaoguo Zhang Cationic-Rhodium-Catalyzed Kinetic Resolution of Allylic Alcohols through a Redox Isomerization Reaction in a Noncoordinating Solvent ChemCatChem 5

Article first published online: 1 MAR 2013 | DOI: 10.1002/cctc.201300014

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On the [Rh]oad again: A series of optically pure allylic alcohols is obtained through the Rh/BINAP-catalyzed redox isomerization of racemic allylic alcohols. An improved system involves the use of cationic rhodium and a noncoordinating solvent, in which aromatic and aliphatic allylic alcohols are effectively resolved with kf/ks (kf=rate of fast reaction, ks=rate of slow reaction) values up to 24.

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