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Dr. Guihua Chen, Kang Chen and Prof. Zhang-Jie Shi Asymmetric Allylic Alkylation of Alkene through Direct C (sp3)-H Functionalization ChemCatChem 5

Article first published online: 28 MAR 2013 | DOI: 10.1002/cctc.201300015

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Put your Trost in this reaction: The first catalytic asymmetric Tsuji–Trost reaction via allylic C[BOND]H activation was realized using a new class of chiral phosphoramidite ligands. This work represents a considerable breakthrough in palladium catalyzed asymmetric allylic C[BOND]H alkylations.

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