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Dr. Nam T. S. Phan, Tung T. Nguyen, Vu T. Nguyen and Khoa D. Nguyen Ligand-Free Copper-Catalyzed Coupling of Phenols with Nitroarenes by using a Metal–Organic Framework as a Robust and Recoverable Catalyst ChemCatChem 5

Article first published online: 22 APR 2013 | DOI: 10.1002/cctc.201300032

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Catalytic MOF: A highly porous metal–organic framework Cu2(BDC)2(DABCO) (H2BDC=1,4-benzenedicarboxylic acid, DABCO=1,4-diazabicyclo[2.2.2]octane) was synthesized and used as an efficient recyclable heterogeneous catalyst for the coupling reaction of phenols with nitroarenes to form diaryl ethers without using a ligand.

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