Dr. Anne-Laure Auvinet, Dr. Mehdi Ez-Zoubir, Savinien Bompard, Dr. Maxime R. Vitale, Jack A. Brown, Dr. Véronique Michelet and Dr. Virginie Ratovelomanana-Vidal Iridium(III)-Catalyzed Approach for the Synthesis of Fused Arenes: Access to Isoindolines, Indanes, and Dihydroisobenzofurans ChemCatChem 5
Triple-edged sword: Isoindoline, indane, and dihydroisobenzofuran derivatives are synthesized by using a triply halogen-bridged iridium(III) complex in the [2+2+2] cycloaddition of α,ω-diynes with alkynes. A broad range of substitution groups such as alcohol, alkyl, ether, and halogen can be used and the chemistry extended to prepare the corresponding borylated fused arenes.
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