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Dr. Yasutaka Kuwahara, Takato Yamanishi, Dr. Takashi Kamegawa, Dr. Kohsuke Mori and Prof. Dr. Hiromi Yamashita Activity, Recyclability, and Stability of Lipases Immobilized on Oil-Filled Spherical Silica Nanoparticles with Different Silica Shell Structures ChemCatChem 5

Version of Record online: 29 APR 2013 | DOI: 10.1002/cctc.201300072

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Trapped oil: Candida antarctica lipase A is immobilized on oil-filled spherical silica nanoparticles with different silica shell structures through an anionic surfactant-induced self-assembly approach (see scheme) with ethanol as a cosolvent. The entrapped enzymes mostly retain their activities and exhibit recyclability and thermal and chemical stability, depending on the thickness and pore characteristics of the silica shells. TEOS=Tetraethoxyorthosilicate, APTES=3-aminopropyl triethoxysilane.

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