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Jian Yang, Dr. Federico Calle-Vallejo, Dr. Matteo Duca and Prof. Marc T. M. Koper Electrocatalytic Reduction of Nitrate on a Pt Electrode Modified by p-Block Metal Adatoms in Acid Solution ChemCatChem 5

Article first published online: 16 MAY 2013 | DOI: 10.1002/cctc.201300075

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Some metals do it better: Polycrystalline platinum electrodes are modified with p-block elements and their abilities for nitrate reduction to volatile nitrogen oxides in perchloric and sulfuric acid solutions investigated. Online electrochemical mass spectrometry is used to detect volatile products on the electrode surface and DFT calculations give insight into the nature of the promoting action.

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