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Han Zhou and Prof. Dr. Hanmin Huang A Ruthenium Catalyst with Simple Triphenylphosphane for the Enantioselective Hydrogenation of Aromatic Ketones ChemCatChem 5

Version of Record online: 8 APR 2013 | DOI: 10.1002/cctc.201300080

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Keep it simple: An efficient Ru catalyst constructed from simple and commercially available triphenylphosphane and enantiopure (1S,1′S)-1,1′-biisoindoline (BIDN) was applied to the asymmetric hydrogenation of aromatic ketones. A range of simple aromatic ketones could be hydrogenated with good to excellent enantioselectivities (up to 95 % ee).

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