Dr. Dennis G. H. Hetterscheid, Dr. Samir H. Chikkali, Prof. Dr. Bas de Bruin and Prof. Dr. Joost N. H. Reek Binuclear Cooperative Catalysts for the Hydrogenation and Hydroformylation of Olefins ChemCatChem 5
Let's cooperate! Cooperative bimetallic catalysis plays an important role in bioenzymatic conversions, and numerous examples are reported in (bio)inorganic and organic chemistry. In organometallic chemistry, this type of catalysis is rare. Here, the concept of cooperative binuclear substrate activation in hydrogenation and hydroformylation reactions is discussed.
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