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Xiaoe Wang, Dr. Chengxia Miao, Shoufeng Wang, Prof. Dr. Chungu Xia and Prof. Dr. Wei Sun Bioinspired Manganese and Iron Complexes with Tetradentate N Ligands for the Asymmetric Epoxidation of Olefins ChemCatChem 5

Version of Record online: 21 MAY 2013 | DOI: 10.1002/cctc.201300102

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Asymmetric barrier overtaken! The manganese and iron complexes with the tetradentate N ligand (1R,2R)-N,N'-dimethyl-N,N'-bis(1-methyl-2-benzimidazolylmethyl)cyclohexane-1,2-diamine have been synthesized and characterized. These complexes are active catalysts for the asymmetric epoxidation of olefins, which resulted in up to 96 % ee.

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