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Le Xu, Ningning Li, Hong-gen Peng and Prof. Peng Wu Clean Synthesis of Amides over Bifunctional Catalysts of Rhodium-Loaded Titanosilicates ChemCatChem 5

Version of Record online: 3 JUN 2013 | DOI: 10.1002/cctc.201300126

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Tandem road: Rhodium-loaded titanosilicates are prepared and employed as efficient bifunctional catalysts in the one-pot synthesis of benzamide from benzaldehyde, hydrogen peroxide, and ammonia, which takes place through a tandem reaction including ammoximation of benzaldehyde to benzaldehyde oxime and a sequential dehydration–rehydration reaction to benzamide.

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