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Dr. Rafique Ul Islam, Dr. Sanjit K. Mahato, Sudheesh K. Shukla, Prof. Michael J. Witcomb and Dr. Kaushik Mallick Palladium–Poly(3-aminoquinoline) Hollow-Sphere Composite: Application in Sonogashira Coupling Reactions ChemCatChem 5

Article first published online: 21 MAY 2013 | DOI: 10.1002/cctc.201300131

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Heart-to-heart cross-coupling: We report on the use of palladium acetate for the synthesis of a palladium-based polymer composite material as a catalyst for Sonogashira cross-coupling reactions for aryl and heteroaryl of iodides and bromides. This composite catalyst is found to be stable and produces a high turnover frequency value under copper-free and ligand-free conditions.

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