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Dr. Feng Li, Panpan Qu, Juan Ma, Xiaoyuan Zou and Chunlou Sun Tandem Synthesis of N-Alkylated Amides from Aldoximes and Alcohols by Using a Ru/Ir Dual-Catalyst System ChemCatChem 5

Article first published online: 6 MAY 2013 | DOI: 10.1002/cctc.201300140

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In the same boat: Tandem rearrangement/N-alkylation reactions in the presence of a Ru/Ir dual-catalyst system affords the desired N-alkylated amines in good-to-excellent yields with no intermediate amides or over-alkylated N,N-dialkylated amides. This environmentally friendly tandem reaction employs readily available starting materials, affords excellent selectivities for the N-alkylated amides, and shows high atom efficiency.

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