Dr. Dawood Elhamifar, Prof. Dr. Babak Karimi, Javad Rastegar and Mohammad Hossain Banakar Palladium-Containing Ionic Liquid-Based Ordered Mesoporous Organosilica: An Efficient and Reusable Catalyst for the Heck Reaction ChemCatChem 5
A Heck of a nanocatalyst! The catalytic application of a novel palladium-containing ionic liquid-based periodic mesoporous organosilica (Pd@PMO-IL-I) in the Heck coupling of different aryl halides with alkyl acrylates has been described. This nanocatalyst demonstrated extremely high reactivity in the Heck reaction of aryl iodides, aryl bromides and aryl chlorides with electron-withdrawing groups. The catalyst could be recovered and reused several times with no decrease in activity.
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