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Dr. Atsushi Ohtaka, Erina Sakaguchi, Tomohiro Yamaguchi, Dr. Go Hamasaka, Prof. Yasuhiro Uozumi, Dr. Osamu Shimomura and Prof. Ryôki Nomura A Recyclable “Boomerang” Linear Polystyrene-Stabilized Pd Nanoparticles for the Suzuki Coupling Reaction of Aryl Chlorides in Water ChemCatChem 5

Article first published online: 16 MAY 2013 | DOI: 10.1002/cctc.201300204

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Boomerang! It keeps coming back! The reversible transfer of Pd species between water (reaction medium) and polystyrene (polymer support) was confirmed for Suzuki coupling reaction of aryl chloride with arylboronic acid in the presence of tetrabutylammonium bromide. No clear change in particle size was observed by TEM after re-stabilization of the Pd species on linear polystyrene.

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