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Vinícius V. Costa, Dr. Kelly A. da Silva Rocha, Rafaela A. Mesquita, Dr. Elena F. Kozhevnikova, Prof. Ivan V. Kozhevnikov and Prof. Elena V. Gusevskaya Heteropoly Acid Catalysts for the Synthesis of Fragrance Compounds from Biorenewables: Cycloaddition of Crotonaldehyde to Limonene, α-Pinene, and β-Pinene ChemCatChem 5

Version of Record online: 14 JUN 2013 | DOI: 10.1002/cctc.201300208

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Low-cost and smells good! Widespread monoterpenes, which are cheap biomass-based substrates available from coniferous trees or citric fruits, can be transformed in fragrant polycyclic products through a simple catalytic process using heteropoly acid H3PW12O40 (HPW) and its cesium salt Cs0.5H0.5PW12O40 (CsPW) as efficient and environmentally benign heterogeneous catalysts.

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