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Hazi Ahmad Beejapur, Dr. Francesco Giacalone, Prof. Renato Noto, Dr. Paola Franchi, Prof. Marco Lucarini and Prof. Michelangelo Gruttadauria Recyclable Catalyst Reservoir: Oxidation of Alcohols Mediated by Noncovalently Supported Bis(imidazolium)-Tagged 2,2,6,6-Tetramethylpiperidine 1-Oxyl ChemCatChem 5

Article first published online: 3 JUN 2013 | DOI: 10.1002/cctc.201300234

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Catch and release: Why spend money on covalent immobilization or ionic liquids with bulky cations? A bis(imidazolium)-modified 2,2,6,6-tetramethylpiperidine 1-oxyl catalyst can be adsorbed on an imidazolium-modified support, then released in the presence of a proper organic solvent and recaptured at the end of the reaction on removal of the solvent.

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