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Prof. Dr. Yujiro Hayashi and Masahiro Kojima Asymmetric Aldol Reaction of Glyoxal Catalyzed by Diarylprolinol ChemCatChem 5

Article first published online: 18 JUN 2013 | DOI: 10.1002/cctc.201300247

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All selection should be this­ eeasy: The direct asymmetric aldol reaction of commercial aqueous glyoxal is catalyzed by trifluoromethyl-substituted diarylprolinol 1 to afford a β-formyl-β-hydroxy-α-substituted aldehyde in good yield with excellent anti selectivity and excellent enantioselectivity.

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