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Dr. Pablo Mauleón Gold-Catalyzed Intermolecular Enantioselective [2+2] Cycloadditions of Sulfonylallenamides and Styrenes ChemCatChem 5

Version of Record online: 5 JUN 2013 | DOI: 10.1002/cctc.201300282

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It′s hip to be square: The search for methods for the enantioselective construction of carbocycles continues to fuel new discoveries. Now, the treatment of mixtures of sulfonylallenamides and styrenes with gold(I)-phosphoramidite complexes results in the formation of cyclobutene carbon frameworks in high yield and optical purity.

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