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Andreas Schönweiz, Jonas Debuschewitz, Simon Walter, Dr. René Wölfel, Hanna Hahn, Katrin M. Dyballa, Prof. Dr. Robert Franke, Dr. Marco Haumann and Prof. Dr. Peter Wasserscheid Ligand-Modified Rhodium Catalysts on Porous Silica in the Continuous Gas-Phase Hydroformylation of Short-Chain Alkenes–Catalytic Reaction in Liquid-Supported Aldol Products ChemCatChem 5

Article first published online: 16 AUG 2013 | DOI: 10.1002/cctc.201300305

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It's all in the pores! Ligand-modified Rh complexes are physically adsorbed onto the surface of porous silica and the resulting solid materials are subjected to continuous gas-phase hydroformylation of C2 and C4 alkenes. The catalyst materials were surprisingly active and, in particular, exhibited similar selectivity to liquid-phase reactions.

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