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Tom E. Stennett, Dr. Thomas W. Hey, Liam T. Ball, Stephanie R. Flynn, James E. Radcliffe, Dr. Claire L. McMullin, Dr. Richard L. Wingad and Prof. Dr. Duncan F. Wass N,N-Diphospholylamines—A New Family of Ligands for Highly Active, Chromium-Based, Selective Ethene Oligomerisation Catalysts ChemCatChem 5

Article first published online: 21 JUN 2013 | DOI: 10.1002/cctc.201300306

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Top hole phosphole! New diphosphazane ligands based on phosphole donors produce highly active catalysts with chromium for the selective oligomerization of ethene. Modification of the backbone nitrogen substituent gives excellent control over the C6/C8 selectivity. MAO=methylaluminoxane.

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