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Dr. Carly E. Anderson, Dr. Sergei I. Vagin, Markus Hammann, Leander Zimmermann and Prof. Dr. Bernhard Rieger Copolymerisation of Propylene Oxide and Carbon Dioxide by Dinuclear Cobalt Porphyrins ChemCatChem 5

Article first published online: 18 SEP 2013 | DOI: 10.1002/cctc.201300307

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Bye bi… Dinuclear biscobalt porphyrins exhibit no improvement in activity for carbon dioxide–propylene oxide copolymerization compared to their mononuclear analogues. These findings disprove the occurrence of the bimetallic mechanism of polycarbonate chain propagation in the case of cobalt porphyrins.

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