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Ronald Carrasquillo-Flores, Dr. Jean Marcel R. Gallo, Dr. Konstanze Hahn, Prof. James A. Dumesic and Prof. Manos Mavrikakis Density Functional Theory and Reaction Kinetics Studies of the Water–Gas Shift Reaction on Pt–Re Catalysts ChemCatChem 5

Article first published online: 5 NOV 2013 | DOI: 10.1002/cctc.201300365

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ReOx decorations in a Pt surface: Pt–Re alloys show high activity for low-temperature water–gas shift reactions. Pt atoms serve as the adsorption site for CO molecules, whereas the Re atoms are determined to be in an oxidized state; they act as a promoter for the reaction, by destabilizing the CO molecules.

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