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Maria Torres, Dr. Aline Maisse-François and Dr. Stéphane Bellemin-Laponnaz Highly Recyclable Self-Supported Chiral Catalysts for the Enantioselective α-Hydrazination of β-Ketoesters ChemCatChem 5

Article first published online: 15 AUG 2013 | DOI: 10.1002/cctc.201300395

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Support group: Multitopic bis(oxazoline)-based chiral ligands are used with copper to generate efficient catalysts for the enantioselective α-hydrazination of β-ketoesters. The catalysts are achieved through the aggregation of copper(II) ions with polytopic ligands. The formation of the metallopolymers has been studied by UV/Vis titrations and nonlinear effect experiments.

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