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Margarita Popova, Alenka Ristić, Matjaž Mazaj, Darja Maučec, Momtchil Dimitrov and Prof. Dr. Nataša Novak Tušar Autoreduction of Copper on Silica and Iron-Functionalized Silica Nanoparticles with Interparticle Mesoporosity ChemCatChem 6

Version of Record online: 20 NOV 2013 | DOI: 10.1002/cctc.201300463

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Copper autoreduction: The nature and reduction properties of copper oxide species are influenced by the peculiarity of the silica nanoparticles with interparticle mesoporosity (KIL-2 structure) and the presence of a second metal (iron) in a silica matrix. The autoreduction of copper oxide species is easier on the FeKIL-2 supported sample in comparison to its KIL-2 supported analogue, whereas the copper-containing KIL-2 sample shows higher catalytic activity in total toluene oxidation.

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