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Dr. Kazuya Yamaguchi, Dr. Ye Wang and Prof. Dr. Noritaka Mizuno A Widely Applicable Regioselective Aerobic α-Cyanation of Tertiary Amines Heterogeneously Catalyzed by Manganese Oxides ChemCatChem 5

Article first published online: 23 JUL 2013 | DOI: 10.1002/cctc.201300477

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A fit catalyst for some aerobic exercise: A manganese oxide-based octahedral molecular sieve, OMS-2, could act as an efficient heterogeneous catalyst for the regioselective α-cyanation of various tertiary amines, including trialkyl, benzylic, and N,N-dialkylaniline derivatives using trimethylsilyl cyanide (TMSCN) as the cyano source and molecular oxygen as the terminal oxidant.

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