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Maxim V. Galkin, Supaporn Sawadjoon, Volker Rohde, Monali Dawange and Dr. Joseph S. M. Samec Mild Heterogeneous Palladium-Catalyzed Cleavage of β-O-4′-Ether Linkages of Lignin Model Compounds and Native Lignin in Air ChemCatChem 6

Article first published online: 4 NOV 2013 | DOI: 10.1002/cctc.201300540

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Green cleavin′ of lignin: A green heterogeneous palladium-catalyzed C[BOND]O bond cleavage of 2-aryloxy-1-arylethanols using formic acid as the reducing agent in air was developed. The cleaved products were isolated in 92–98 % yield, and by slightly varying the reaction conditions, a ketone, an alcohol, or an alkane can be generated in near quantitative yield.

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