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Dr. Hiroyoshi Esaki, Tomohiro Hattori, Aya Tsubone, Satoko Mibayashi, Dr. Takao Sakata, Dr. Yoshinari Sawama, Dr. Yasunari Monguchi, Prof. Dr. Hidehiro Yasuda, Prof. Dr. Kazuto Nosaka and Prof. Dr. Hironao Sajiki Chemoselective Hydrogenation Catalyzed by Pd on Spherical Carbon ChemCatChem 5

Version of Record online: 25 SEP 2013 | DOI: 10.1002/cctc.201300639

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Highly selective spheres: The chemoselective hydrogenation of C[BOND]C multiple bonds, azides, nitro groups, and aliphatic O-tert-butyldimethylsilyl (TBS) ethers is achieved in the presence of benzyl esters, benzyl ethers, nitriles, aromatic ketones, N-carbobenzyloxy (Cbz) protective groups, and aromatic O-TBS ethers by a novel heterogeneous palladium catalyst supported on spherical carbon (0.5 % Pd/SC).

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