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Dr. Toshifumi Dohi and Prof. Dr. Yasuyuki Kita New Site-Selective Organoradical Based on Hypervalent Iodine Reagent for Controlled Alkane sp3 C[BOND]H Oxidations ChemCatChem 6

Article first published online: 18 SEP 2013 | DOI: 10.1002/cctc.201300666

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Large Iodine: The site-selective oxidation of unactivated secondary sp3 C[BOND]H bonds was accomplished by using a newly defined reactive hypervalent iodine(III) radical in the presence of tert-butyl hydroperoxide (see scheme). Recent studies on hypervalent iodine radicals have significantly contributed to the further development and design of organic molecules in radical oxidation chemistry.

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