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Zhi-Jun Du, Prof. Lian-Xun Gao, Prof. Ying-Jie Lin and Prof. Fu-She Han Cu-Mediated Direct Aryl C[BOND]H Halogenation: a Strategy to Control Mono- and Di-Selectivity ChemCatChem 6

Version of Record online: 31 OCT 2013 | DOI: 10.1002/cctc.201300734

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The halogen protocol: A protocol for the copper-mediated direct aryl C[BOND]H halogenation is presented. Highly selective mono- and di-halogenation were achieved efficiently by using acyl hypohalites, generated in situ from the readily available carboxylic acid and NXS (X=Br and Cl), as the powerful halogenating reagents.

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