Jeroen Lauwaert, Els De Canck, Dr. Dolores Esquivel, Prof. Dr. Joris W. Thybaut, Prof. Dr. Pascal Van Der Voort and Prof. Dr. Guy B. Marin Silanol-Assisted Aldol Condensation on Aminated Silica: Understanding the Arrangement of Functional Groups ChemCatChem 6
Let's troop together: The enhancing effect of free silanol groups on amine-catalyzed aldol condensations is studied in great detail. It is concluded that at high amine loadings the amine functions tend to cluster on the catalyst surface.
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