E-mail a Wiley Online Library Link

Lingjuan Zhang, Zhen Jiang, Chaonan Dong, Xiao Xue, Ruiying Qiu, Dr. Weijun Tang, Dr. Huanrong Li, Prof. Jianliang Xiao and Prof. Lijin Xu Palladium-Catalyzed Highly Regioselective Mizoroki–Heck Arylation of Allylamines with Aryl Chlorides ChemCatChem 6

Version of Record online: 13 NOV 2013 | DOI: 10.1002/cctc.201300755

Thumbnail image of graphical abstract

Ferrocene 'cross the Mersey: The combination of Pd(OAc)2 with appropriate additives catalyzes the regio- and stereocontrolled linear arylation of N,N-diprotected allylamines with aryl chlorides in toluene, whereas, in a catalytic mixture of Pd(OAc)2 and 1,1'-bis(diphenylphosphino)ferrocene (dppf), the internal arylation of N-protected allylamines with aryl chlorides is achieved in ethylene glycol (EG)/DMSO with high yields and complete regioselectivity. FG=functional group.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field