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Lingjuan Zhang, Zhen Jiang, Chaonan Dong, Xiao Xue, Ruiying Qiu, Dr. Weijun Tang, Dr. Huanrong Li, Prof. Jianliang Xiao and Prof. Lijin Xu Palladium-Catalyzed Highly Regioselective Mizoroki–Heck Arylation of Allylamines with Aryl Chlorides ChemCatChem 6

Article first published online: 13 NOV 2013 | DOI: 10.1002/cctc.201300755

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Ferrocene 'cross the Mersey: The combination of Pd(OAc)2 with appropriate additives catalyzes the regio- and stereocontrolled linear arylation of N,N-diprotected allylamines with aryl chlorides in toluene, whereas, in a catalytic mixture of Pd(OAc)2 and 1,1'-bis(diphenylphosphino)ferrocene (dppf), the internal arylation of N-protected allylamines with aryl chlorides is achieved in ethylene glycol (EG)/DMSO with high yields and complete regioselectivity. FG=functional group.

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