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Amal Cherian Kathalikkattil, Roshith Roshan, Dr. Jose Tharun, Han-Geul Soek, Hyeong-Seok Ryu and Prof. Dae-Won Park Pillared Cobalt–Amino Acid Framework Catalysis for Styrene Carbonate Synthesis from CO2 and Epoxide by Metal–Sulfonate–Halide Synergism ChemCatChem 6

Version of Record online: 11 DEC 2013 | DOI: 10.1002/cctc.201300756

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May ion introduce you? Sulfonate anions are introduced to CO2-fixation catalysis for cyclic carbonate synthesis at atmospheric pressure through a metal–sulfonate synergistic mechanism by means of a cobalt–amino acid coordination framework catalyst. 2 D-CCB=[{Co(4,4′-bipy)(L-cys)(H2O)}H2O]n; TBAB=tetra-n-butylammonium bromide.

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