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Dr. Marloes Schurink, Dr. Suzanne Wolterink-van Loo, Prof. Dr. John van der Oost, Dr. Theo Sonke and Dr. Maurice C. R. Franssen Substrate Specificity and Stereoselectivity of Two Sulfolobus 2-Keto-3-deoxygluconate Aldolases towards Azido-Substituted Aldehydes ChemCatChem 6

Version of Record online: 5 MAR 2014 | DOI: 10.1002/cctc.201300785

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Taming the wild-type: Two 2-keto-3-deoxygluconate aldolases from Sulfolobus species readily couple azido-substituted aldehydes to pyruvate in a stereoselective manner. The resulting compounds yield chiral nitrogen heterocycles upon reduction.

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