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Iván Ayuso-Fernández, Miquel A. Galmés, Dr. Agatha Bastida and Dr. Eduardo García-Junceda Aryl Sulfotransferase from Haliangium ochraceum: A Versatile Tool for the Sulfation of Small Molecules ChemCatChem 6

Version of Record online: 26 MAR 2014 | DOI: 10.1002/cctc.201300853

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Sulfation variations: We prove experimentally that the gene Hoch_5094 from Haliangium ochraceum encodes for an aryl sulfotransferase. The codified enzyme, HocAST, may be a very versatile biocatalyst as it is able to use both p- nitrophenyl sulfate (p-NPS) and 3′-phosphoadenosine-5′-phosphosulfate (PAPS) as donors and transfer the sulfuryl group to several phenolic compounds and biologically relevant phosphorylated molecules. GTP(S)=Guanosine-5′- triphosphate(-5′-sulfate), BiPhOH= 4,4'-Biphenol, BiPhOS=4,4'-Biphenol 4-sulfate.

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