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Youkun Tao, Dr. Sune D. Ebbesen, Dr. Wei Zhang and Prof. Dr. Mogens B. Mogensen Carbon Nanotube Growth on Nanozirconia under Strong Cathodic Polarization in Steam and Carbon Dioxide ChemCatChem 6

Version of Record online: 23 FEB 2014 | DOI: 10.1002/cctc.201300941

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Zap it! This work describes nanozirconia acting as a catalyst for the growth of carbon nanotubes (CNTs) during electrochemical conversion of carbon dioxide and water in a nickel–yttria-stabilized zirconia cermet under strong cathodic polarization. An electrocatalytic mechanism is proposed for the growth of the CNTs. equation image=Oxygen vacancy, equation image=occupied site of oxygen in zirconia.

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