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Siah Pei Shan, Dr. Tuan Thanh Dang, Dr. Abdul Majeed Seayad and Dr. Balamurugan Ramalingam Reusable Supported Ruthenium Catalysts for the Alkylation of Amines by using Primary Alcohols ChemCatChem 6

Version of Record online: 27 JAN 2014 | DOI: 10.1002/cctc.201300971

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Support group steals the show: An efficient Ru-based heterogeneous catalyst from readily available supported phosphine ligands is developed. The nature of the linkage and the extent of ruthenium incorporation are crucial in determining the catalytic activity. The catalyst can be recycled and used under continuous flow in a packed-bed reactor. The alkylation of cyclic amines is achieved in excellent yield at moderate temperatures in the absence of any external base.

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