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Dr. Sanjit K. Mahato, Dr. Rafique Ul Islam, Chiranjit Acharya, Prof. Michael J. Witcomb and Prof. Kaushik Mallick Polymer-Stabilized Palladium Nanoparticles for the Chemoselective Transfer Hydrogenation of α,β-Unsaturated Carbonyls: Single-Step Bottom-Up Approach ChemCatChem 6

Version of Record online: 19 MAR 2014 | DOI: 10.1002/cctc.201300985

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Podium position for palladium: A palladium–polypyrrole composite is synthesized for the chemoselective transfer hydrogenation of α,β-unsaturated carbonyl compounds by using an in situ polymerisation and composite formation method. No semi-hydrogenated product was observed with alkyne systems and hydrodehalogenation of the haloarene segment of the substrate was not encountered in reactions with this catalyst.

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